全文获取类型
收费全文 | 42572篇 |
免费 | 5732篇 |
国内免费 | 2219篇 |
专业分类
电工技术 | 874篇 |
技术理论 | 1篇 |
综合类 | 3022篇 |
化学工业 | 13538篇 |
金属工艺 | 9576篇 |
机械仪表 | 3248篇 |
建筑科学 | 2922篇 |
矿业工程 | 1298篇 |
能源动力 | 726篇 |
轻工业 | 1680篇 |
水利工程 | 526篇 |
石油天然气 | 835篇 |
武器工业 | 688篇 |
无线电 | 1256篇 |
一般工业技术 | 6895篇 |
冶金工业 | 2629篇 |
原子能技术 | 166篇 |
自动化技术 | 643篇 |
出版年
2024年 | 162篇 |
2023年 | 960篇 |
2022年 | 1406篇 |
2021年 | 2056篇 |
2020年 | 1850篇 |
2019年 | 1458篇 |
2018年 | 1525篇 |
2017年 | 1886篇 |
2016年 | 1885篇 |
2015年 | 1932篇 |
2014年 | 2367篇 |
2013年 | 2593篇 |
2012年 | 3139篇 |
2011年 | 3105篇 |
2010年 | 2322篇 |
2009年 | 2425篇 |
2008年 | 2018篇 |
2007年 | 2716篇 |
2006年 | 2684篇 |
2005年 | 2036篇 |
2004年 | 1860篇 |
2003年 | 1446篇 |
2002年 | 1205篇 |
2001年 | 1064篇 |
2000年 | 829篇 |
1999年 | 599篇 |
1998年 | 539篇 |
1997年 | 416篇 |
1996年 | 401篇 |
1995年 | 321篇 |
1994年 | 310篇 |
1993年 | 195篇 |
1992年 | 175篇 |
1991年 | 129篇 |
1990年 | 134篇 |
1989年 | 163篇 |
1988年 | 31篇 |
1987年 | 37篇 |
1986年 | 22篇 |
1985年 | 25篇 |
1984年 | 24篇 |
1983年 | 20篇 |
1982年 | 20篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1974年 | 2篇 |
1966年 | 2篇 |
1959年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Ib Holzmeister Jan Weichhold Jürgen Groll Hala Zreiqat Uwe Gbureck 《Journal of the American Ceramic Society》2021,104(7):3554-3561
In this study, the hydraulic reactivity and cement formation of baghdadite (Ca3ZrSi2O9) was investigated. The material was synthesized by sintering a mixture of CaCO3, SiO2, and ZrO2 and then mechanically activated using a planetary mill. This leads to a decrease in particle and crystallite size and a partial amorphization of baghdadite as shown by X-ray powder diffraction (XRD) and laser diffraction measurements. Baghdadite cements were formed by the addition of water at a powder to liquid ratio of 2.0 g/ml. Maximum compressive strengths were found to be ~2 MPa after 3-day setting for a 24-h ground material. Inductively coupled plasma mass spectrometry (ICP-MS) measurements showed an incongruent dissolution profile of set cements with a preferred dissolution of calcium and only marginal release of zirconium ions. Cement formation occurs under alkaline conditions, whereas the unground raw powder leads to a pH of 11.9 during setting, while prolonged grinding increased pH values to approximately 12.3. 相似文献
22.
23.
《岩石力学与岩土工程学报(英文版)》2022,14(3):813-824
Based on the nondestructive test data of operating railway tunnels in China, this paper summarizes the basic characteristics of the complex contact behavior between the rock mass and lining structure. The contact modes are classified into dense contact, local non-contact, and loose contact. Subsequently, the corresponding mechanical model for each contact mode is developed according to its mechanical characteristics using the complex variable method. In the proposed mechanical model, a special algorithm is introduced to detect whether the local non-contact zone is re-contacted. Besides, a novel conformal mapping method is also proposed to accurately calculate the mechanical response of the concrete lining. Finally, the accuracy of the proposed method is verified by comparing it with the finite element method (FEM). Several parameter investigations are conducted to analyze the effects of different contact modes on the rock–lining interaction. The results show that: (i) the height of the local non-contact area does not have a significant effect on the contact stress distribution if no re-contact occurs; (ii) backfill grouting can reduce the local stress concentration caused by poor contact modes; and (iii) reducing the friction coefficient of the interface can lead to a more uniform distribution of internal forces in the concrete lining. 相似文献
24.
Jianrong Xia Hanyu Xue Renjin Gao Yuchi Zhang Qi Lin 《Polymer Engineering and Science》2021,61(2):489-496
The over-exploitation of finite fossil resources and/or the increased environmental and sustainable awareness inspire scientists and technologists to search for inexpensive alternatives from renewable chemicals. Phenol formaldehyde (PF) resins, the oldest type of synthetic polymers with good mechanical properties and heat resistance, are widely used in the production of coatings, laminates, molding compositions, and glues. Here, biobased urushiol-derived PF resins were synthesized from the alkali-catalyzed reaction between urushiol and formaldehyde. The chemical compositions and molecular structures of resole resins were characterized by carbon-13 nuclear magnetic resonance and Fourier transform infrared spectroscopy, and their curing behaviors were studied by differential scanning calorimetry. The as-prepared urushiol-derived resole resins had methylol (Ph−CH2OH), ortho- and para-hemiformal groups (Ph−CH2OCH2OH), and the para−para/ortho−para/ortho−ortho links of methylene groups (Ph−CH2−Ph), whereas the resole resins had low curing temperatures at about 100–113°C. Additionally, given the long side alkyl group moiety on the aromatic rings of urushiol, the films of cured urushiol-derived resole resins had low glass transition temperatures of 132 ± 2°C. Furthermore, the as-prepared urushiol-derived coatings exhibited excellent physical and mechanical properties. 相似文献
25.
An instrumented hot compression molding apparatus was fabricated to allow real-time monitoring and precise temperature control during the compaction and consolidation of large polyether ether ketone (PEEK) products. The objective was to determine the impact of controlled variables on the properties of the molded article. Four different strategies were designed to control the mold thermal profiles. The average crystallinity in a commercial molding process is restricted due to large thermal masses with low thermal conductivity. In contrast, this research was able to reduce the crystallinity range from 33% to 6% by developing a special controlled apparatus and implementing new processing methodologies. In this study, PEEK showed a significant increase in the modulus compared to typical values measured on commercially produced analogs, and a higher degree of property uniformity. In a single commercially molded PEEK billet, compressive modulus variability was 13% at room temperature, and 21% at 225°C. Properties of billets produced using the laboratory apparatus showed a reduction in variability to 2%. 相似文献
26.
In this article, we have studied the effect of carbonaceous nanofillers viz. fullerenol (0D), carboxylated multi-wall carbon nanotube (MWCNT, 1D), hydroxylated graphene (2D) and combination of carboxylated CNT and hydroxylated graphene as 3D in thermoplastic polyurethane on the tensile properties of the fabricated cellular structures. The concentration of nano-fillers was varied as 0.1, 1, and 5 wt%. Tensile properties of the nanocomposite cellular structures were measured as per ASTM D882 at 20°C (below glass transition temperature, Tg) and 40°C (above Tg). The results have shown that the tensile strength was found to increase by 200%–300% and the tensile modulus was found to increase by 150%–300% for 2D and 3D nano-fillers while significantly poor results were observed for 0D. However, the test data tensile strength and modulus showed marginal increase at 20°C and marginally low at 40°C for 1D filler. The interfacial adhesion was calculated by using experimental tensile data and the predictive models. The interfacial adhesion parameter (Bσ) calculated using Pukanszky equation was found significantly higher value for 2D (Bσ20 = 195.8) and 3D (Bσ20 = 192.0) fillers while poor adhesion was observed for 0D (Bσ20 = −81.6) fillers. The developed cellular structured materials were also evaluated by attenuated total reflection Fourier transform IR spectra, differential scanning calorimetry, X-ray diffraction, scanning electron microscope, and transmission electron microscope. 相似文献
27.
28.
29.
Virginija Sacevičienė Milda Jucienė Vaida Dobilaitė Valentina Krylova Skirma Žalenkienė Nijolė Dukštienė Raimondas Bliūdžius 《应用聚合物科学杂志》2019,136(21):47523
The aim of this work was to investigate the physical and mechanical performance of architectural polyester (PES)–poly(vinyl chloride) (PVC) membranes exposed to different artificial aging conditions. Two commercially available architectural membranes were chosen as research objects. The durability of the PES/PVC fabrics was evaluated by the loss in mechanical performance, scanning electron microscopy, and X-ray diffraction analysis in order to understand the effect of the degradation agents on the surface of the membranes. The mechanical performance of the PES/PVC membranes was unchanged. Scanning electron microscopy images of the tested materials showed initial cracks after aging. The X-ray fluorescence analysis showed that at the time of aging, the amount of Cl and Si decreased slightly, while Ti decreased by half, and Ca by volume increased twice. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47523. 相似文献
30.
以微米级氧化钒(V2O5)、氧化铬(Cr2O3)和纳米碳黑为原料,采用机械合金化及微波辅助加热法制备了纳米碳化钒/碳化铬复合粉末。利用XRD、XPS、TG-DSC、SEM、TEM和BET对产物进行了分析表征。结果表明,:纳米碳化钒/碳化铬复合粉末的最佳合成条件为:碳的质量分数为35%,反应温度为900℃,保温时间为1h。在该条件下的反应产物主要由V3Cr2C5、Cr2VC2和Cr3C2组成,颗粒为球形或类球形,分散性较好,无明显团聚现象,平均颗粒尺寸约为50nm,复合粉末的比表面积为115.53m2/g。添加纳米碳化钒/碳化铬复合粉末可以提高陶瓷结合剂cBN磨具的力学性能和磨削效率,降低磨具的损耗,并且对磨具具有减摩作用。 相似文献